VY 6002 then FR 9601 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
11:05VY 6002 from Barcelona at the gate
06:10FR 9601 to Madrid leaves the gate
19 h 05 apart on the timetable, overnight
FR 9601 leaves 19 h 05 after VY 6002 arrives on the timetable: more than half a day, so not a connection we count.