VY 6006 then FR 9601 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
11:50VY 6006 from Barcelona at the gate
09:00FR 9601 to Madrid leaves the gate
21 h 10 apart on the timetable, overnight
FR 9601 leaves 21 h 10 after VY 6006 arrives on the timetable: more than half a day, so not a connection we count.