VY 6010 then FR 9601 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
14:40VY 6010 from Barcelona at the gate
09:00FR 9601 to Madrid leaves the gate
18 h 20 apart on the timetable, overnight
FR 9601 leaves 18 h 20 after VY 6010 arrives on the timetable: more than half a day, so not a connection we count.