VY 6014 then FR 4861 at Fiumicino
Barcelona → Rome → Catania
Timetable, Rome time
19:05VY 6014 from Barcelona at the gate
19:00FR 4861 to Catania leaves the gate
23 h 55 apart on the timetable, overnight
FR 4861 leaves 23 h 55 after VY 6014 arrives on the timetable: more than half a day, so not a connection we count.