W4 2445 then W4 6027 at Fiumicino
Timisoara → Rome → Valencia
Timetable, Rome time
13:15W4 2445 from Timisoara at the gate
12:35W4 6027 to Valencia leaves the gate
23 h 20 apart on the timetable, overnight
W4 6027 leaves 23 h 20 after W4 2445 arrives on the timetable: more than half a day, so not a connection we count.