W4 6012 then EW 8883 at Fiumicino
Madrid → Rome → Berlin
Timetable, Rome time
11:55W4 6012 from Madrid at the gate
10:20EW 8883 to Berlin leaves the gate
22 h 25 apart on the timetable, overnight
EW 8883 leaves 22 h 25 after W4 6012 arrives on the timetable: more than half a day, so not a connection we count.