W4 6028 then FR 5316 at Fiumicino
Valencia → Rome → Madrid
Timetable, Rome time
17:35W4 6028 from Valencia at the gate
05:45FR 5316 to Madrid leaves the gate
12 h 10 apart on the timetable, overnight
FR 5316 leaves 12 h 10 after W4 6028 arrives on the timetable: more than half a day, so not a connection we count.