W4 6030 then EW 887 at Fiumicino
Valencia → Rome → Cologne
Timetable, Rome time
10:40W4 6030 from Valencia at the gate
09:45EW 887 to Cologne leaves the gate
23 h 05 apart on the timetable, overnight
EW 887 leaves 23 h 05 after W4 6030 arrives on the timetable: more than half a day, so not a connection we count.