W4 6030 then EW 8883 at Fiumicino
Valencia → Rome → Berlin
Timetable, Rome time
10:40W4 6030 from Valencia at the gate
10:20EW 8883 to Berlin leaves the gate
23 h 40 apart on the timetable, overnight
EW 8883 leaves 23 h 40 after W4 6030 arrives on the timetable: more than half a day, so not a connection we count.