W4 6030 then FR 9601 at Fiumicino
Valencia → Rome → Madrid
Timetable, Rome time
10:40W4 6030 from Valencia at the gate
09:00FR 9601 to Madrid leaves the gate
22 h 20 apart on the timetable, overnight
FR 9601 leaves 22 h 20 after W4 6030 arrives on the timetable: more than half a day, so not a connection we count.