W4 6066 then FR 4005 at Fiumicino
Prague → Rome → Alicante
Timetable, Rome time
16:55W4 6066 from Prague at the gate
15:05FR 4005 to Alicante leaves the gate
22 h 10 apart on the timetable, overnight
FR 4005 leaves 22 h 10 after W4 6066 arrives on the timetable: more than half a day, so not a connection we count.