W4 6166 then FR 5316 at Fiumicino
Brasov → Rome → Madrid
Timetable, Rome time
10:30W4 6166 from Brasov at the gate
10:20FR 5316 to Madrid leaves the gate
23 h 50 apart on the timetable, overnight
FR 5316 leaves 23 h 50 after W4 6166 arrives on the timetable: more than half a day, so not a connection we count.