W4 6220 then FR 4861 at Fiumicino
Lisbon → Rome → Catania
Timetable, Rome time
13:10W4 6220 from Lisbon at the gate
09:15FR 4861 to Catania leaves the gate
20 h 05 apart on the timetable, overnight
FR 4861 leaves 20 h 05 after W4 6220 arrives on the timetable: more than half a day, so not a connection we count.