W4 7039 then U2 5080 at Fiumicino
Milan → Rome → Berlin
Timetable, Rome time
09:00W4 7039 from Milan at the gate
08:45U2 5080 to Berlin leaves the gate
23 h 45 apart on the timetable, overnight
U2 5080 leaves 23 h 45 after W4 7039 arrives on the timetable: more than half a day, so not a connection we count.