AD 4831 then LA 8076 at Guarulhos
Curitiba → São Paulo → Madrid
Timetable, São Paulo time
22:30AD 4831 from Curitiba at the gate
21:25LA 8076 to Madrid leaves the gate
22 h 55 apart on the timetable, overnight
LA 8076 leaves 22 h 55 after AD 4831 arrives on the timetable: more than half a day, so not a connection we count.