UX 57 then JJ 4550 at Guarulhos
Madrid → São Paulo → Curitiba
Timetable, São Paulo time
06:30UX 57 from Madrid at the gate
18:40JJ 4550 to Curitiba leaves the gate
12 h 10 apart on the timetable
JJ 4550 leaves 12 h 10 after UX 57 arrives on the timetable: more than half a day, so not a connection we count.