AA 5332 then UA 3515 at Dulles
Charlotte → Washington → Toronto Pearson
Timetable, Washington time
08:17AA 5332 from Charlotte at the gate
22:10UA 3515 to Toronto Pearson leaves the gate
13 h 53 apart on the timetable
UA 3515 leaves 13 h 53 after AA 5332 arrives on the timetable: more than half a day, so not a connection we count.