AA 3232 then UA 62 at Houston
Phoenix → Houston → São Paulo
Timetable, Houston time
23:54AA 3232 from Phoenix at the gate
20:45UA 62 to São Paulo leaves the gate
20 h 51 apart on the timetable, overnight
UA 62 leaves 20 h 51 after AA 3232 arrives on the timetable: more than half a day, so not a connection we count.