DP 995 then TK 223 at Istanbul
Moscow Vnukovo → Istanbul → Caracas
Timetable, Istanbul time
16:10DP 995 from Moscow Vnukovo at the gate
15:30TK 223 to Caracas leaves the gate
23 h 20 apart on the timetable, overnight
TK 223 leaves 23 h 20 after DP 995 arrives on the timetable: more than half a day, so not a connection we count.