4Z 754 then FA 107 at Johannesburg
Mthatha → Johannesburg → Cape Town
Timetable, Johannesburg time
09:504Z 754 from Mthatha at the gate
08:40FA 107 to Cape Town leaves the gate
22 h 50 apart on the timetable, overnight
FA 107 leaves 22 h 50 after 4Z 754 arrives on the timetable: more than half a day, so not a connection we count.