5Z 453 then SA 355 at Johannesburg
George → Johannesburg → Cape Town
Timetable, Johannesburg time
17:255Z 453 from George at the gate
16:40SA 355 to Cape Town leaves the gate
23 h 15 apart on the timetable, overnight
SA 355 leaves 23 h 15 after 5Z 453 arrives on the timetable: more than half a day, so not a connection we count.