5Z 765 then FA 121 at Johannesburg
Victoria Falls → Johannesburg → Cape Town
Timetable, Johannesburg time
14:005Z 765 from Victoria Falls at the gate
13:25FA 121 to Cape Town leaves the gate
23 h 25 apart on the timetable, overnight
FA 121 leaves 23 h 25 after 5Z 765 arrives on the timetable: more than half a day, so not a connection we count.