FA 225 then 4Z 931 at Johannesburg
George → Johannesburg → Cape Town
Timetable, Johannesburg time
16:40FA 225 from George at the gate
15:054Z 931 to Cape Town leaves the gate
22 h 25 apart on the timetable, overnight
4Z 931 leaves 22 h 25 after FA 225 arrives on the timetable: more than half a day, so not a connection we count.