FA 825 then FA 214 at Johannesburg
Victoria Falls → Johannesburg → Cape Town
Timetable, Johannesburg time
17:30FA 825 from Victoria Falls at the gate
16:20FA 214 to Cape Town leaves the gate
22 h 50 apart on the timetable, overnight
FA 214 leaves 22 h 50 after FA 825 arrives on the timetable: more than half a day, so not a connection we count.