LA 8058 then SA 327 at Johannesburg
São Paulo → Johannesburg → Cape Town
Timetable, Johannesburg time
12:45LA 8058 from São Paulo at the gate
11:10SA 327 to Cape Town leaves the gate
22 h 25 apart on the timetable, overnight
SA 327 leaves 22 h 25 after LA 8058 arrives on the timetable: more than half a day, so not a connection we count.