SA 41 then 5Z 108 at Johannesburg
Victoria Falls → Johannesburg → Bloemfontain
Timetable, Johannesburg time
16:05SA 41 from Victoria Falls at the gate
15:305Z 108 to Bloemfontain leaves the gate
23 h 25 apart on the timetable, overnight
5Z 108 leaves 23 h 25 after SA 41 arrives on the timetable: more than half a day, so not a connection we count.