SA 41 then GE 133 at Johannesburg
Victoria Falls → Johannesburg → Cape Town
Timetable, Johannesburg time
16:05SA 41 from Victoria Falls at the gate
16:00GE 133 to Cape Town leaves the gate
23 h 55 apart on the timetable, overnight
GE 133 leaves 23 h 55 after SA 41 arrives on the timetable: more than half a day, so not a connection we count.