SA 41 then SA 343 at Johannesburg
Victoria Falls → Johannesburg → Cape Town
Timetable, Johannesburg time
16:05SA 41 from Victoria Falls at the gate
14:30SA 343 to Cape Town leaves the gate
22 h 25 apart on the timetable, overnight
SA 343 leaves 22 h 25 after SA 41 arrives on the timetable: more than half a day, so not a connection we count.