SA 531 then 5Z 100 at Johannesburg
Livingstone → Johannesburg → Bloemfontain
Timetable, Johannesburg time
06:30SA 531 from Livingstone at the gate
06:255Z 100 to Bloemfontain leaves the gate
23 h 55 apart on the timetable, overnight
5Z 100 leaves 23 h 55 after SA 531 arrives on the timetable: more than half a day, so not a connection we count.