EC 8306 then U2 8229 at Gatwick
Milan → London → Rhodes
Timetable, London time
14:20EC 8306 from Milan at the gate
14:10U2 8229 to Rhodes leaves the gate
23 h 50 apart on the timetable, overnight
U2 8229 leaves 23 h 50 after EC 8306 arrives on the timetable: more than half a day, so not a connection we count.