EC 8628 then LS 3107 at Gatwick
Berlin → London → Alicante
Timetable, London time
08:00EC 8628 from Berlin at the gate
06:20LS 3107 to Alicante leaves the gate
22 h 20 apart on the timetable, overnight
LS 3107 leaves 22 h 20 after EC 8628 arrives on the timetable: more than half a day, so not a connection we count.