AC 888 then VL 2471 at Heathrow
Ottawa → London → Munich
Timetable, London time
09:20AC 888 from Ottawa at the gate
08:45VL 2471 to Munich leaves the gate
23 h 25 apart on the timetable, overnight
VL 2471 leaves 23 h 25 after AC 888 arrives on the timetable: more than half a day, so not a connection we count.