BA 581 then VL 2475 at Heathrow
Milan → London → Munich
Timetable, London time
13:55BA 581 from Milan at the gate
13:50VL 2475 to Munich leaves the gate
23 h 55 apart on the timetable, overnight
VL 2475 leaves 23 h 55 after BA 581 arrives on the timetable: more than half a day, so not a connection we count.