BA 585 then BA 45 at Heathrow
Milan Linate → London → Cape Town
Timetable, London time
21:30BA 585 from Milan Linate at the gate
20:40BA 45 to Cape Town leaves the gate
23 h 10 apart on the timetable, overnight
BA 45 leaves 23 h 10 after BA 585 arrives on the timetable: more than half a day, so not a connection we count.