EW 7462 then BA 410 at Heathrow
Hamburg → London → Valencia
Timetable, London time
15:05EW 7462 from Hamburg at the gate
14:25BA 410 to Valencia leaves the gate
23 h 20 apart on the timetable, overnight
BA 410 leaves 23 h 20 after EW 7462 arrives on the timetable: more than half a day, so not a connection we count.