EW 8460 then BA 592 at Heathrow
Berlin → London → Venezia
Timetable, London time
08:00EW 8460 from Berlin at the gate
07:30BA 592 to Venezia leaves the gate
23 h 30 apart on the timetable, overnight
BA 592 leaves 23 h 30 after EW 8460 arrives on the timetable: more than half a day, so not a connection we count.