EW 9460 then BA 490 at Heathrow
Düsseldorf → London → Gibraltar
Timetable, London time
07:25EW 9460 from Düsseldorf at the gate
06:35BA 490 to Gibraltar leaves the gate
23 h 10 apart on the timetable, overnight
BA 490 leaves 23 h 10 after EW 9460 arrives on the timetable: more than half a day, so not a connection we count.