VS 104 then BA 546 at Heathrow
Atlanta → London → Bologna
Timetable, London time
06:25VS 104 from Atlanta at the gate
20:25BA 546 to Bologna leaves the gate
14 h apart on the timetable
BA 546 leaves 14 h after VS 104 arrives on the timetable: more than half a day, so not a connection we count.