VS 92 then BA 592 at Heathrow
Orlando → London → Venezia
Timetable, London time
09:50VS 92 from Orlando at the gate
07:55BA 592 to Venezia leaves the gate
22 h 05 apart on the timetable, overnight
BA 592 leaves 22 h 05 after VS 92 arrives on the timetable: more than half a day, so not a connection we count.