LA 2121 then PU 302 at Lima
Cusco → Lima → Madrid
Timetable, Lima time
19:35LA 2121 from Cusco at the gate
19:10PU 302 to Madrid leaves the gate
23 h 35 apart on the timetable, overnight
PU 302 leaves 23 h 35 after LA 2121 arrives on the timetable: more than half a day, so not a connection we count.