TP 531 then EW 9603 at Lisbon
Berlin → Lisbon → Düsseldorf
Timetable, Lisbon time
15:40TP 531 from Berlin at the gate
13:30EW 9603 to Düsseldorf leaves the gate
21 h 50 apart on the timetable, overnight
EW 9603 leaves 21 h 50 after TP 531 arrives on the timetable: more than half a day, so not a connection we count.