2W 2094 then DE 9365 at Madrid
Cali → Madrid → Munich
Timetable, Madrid time
12:052W 2094 from Cali at the gate
03:45DE 9365 to Munich leaves the gate
15 h 40 apart on the timetable, overnight
DE 9365 leaves 15 h 40 after 2W 2094 arrives on the timetable: more than half a day, so not a connection we count.