2W 2094 then IB 597 at Madrid
Cali → Madrid → Brussels
Timetable, Madrid time
12:052W 2094 from Cali at the gate
09:05IB 597 to Brussels leaves the gatealso LA 1568, VY 5094, BT 5137
21 h apart on the timetable, overnight
IB 597 leaves 21 h after 2W 2094 arrives on the timetable: more than half a day, so not a connection we count.