2W 2094 then SN 3732 at Madrid
Cali → Madrid → Brussels
Timetable, Madrid time
12:052W 2094 from Cali at the gate
06:25SN 3732 to Brussels leaves the gate
18 h 20 apart on the timetable, overnight
SN 3732 leaves 18 h 20 after 2W 2094 arrives on the timetable: more than half a day, so not a connection we count.