2W 2094 then VL 1807 at Madrid
Cali → Madrid → Munich
Timetable, Madrid time
12:052W 2094 from Cali at the gate
07:25VL 1807 to Munich leaves the gate
19 h 20 apart on the timetable, overnight
VL 1807 leaves 19 h 20 after 2W 2094 arrives on the timetable: more than half a day, so not a connection we count.