3O 391 then FR 5462 at Madrid
Tangier → Madrid → Brussels Charleroi
Timetable, Madrid time
16:253O 391 from Tangier at the gate
14:45FR 5462 to Brussels Charleroi leaves the gate
22 h 20 apart on the timetable, overnight
FR 5462 leaves 22 h 20 after 3O 391 arrives on the timetable: more than half a day, so not a connection we count.