A3 4034 then FR 1206 at Madrid
Athens → Madrid → Venezia
Timetable, Madrid time
19:50A3 4034 from Athens at the gate
10:20FR 1206 to Venezia leaves the gate
14 h 30 apart on the timetable, overnight
FR 1206 leaves 14 h 30 after A3 4034 arrives on the timetable: more than half a day, so not a connection we count.