AA 740 then FR 1206 at Madrid
Philadelphia → Madrid → Venezia
Timetable, Madrid time
08:55AA 740 from Philadelphia at the gatealso BA 1605, AY 3812, IB 4674
22:25FR 1206 to Venezia leaves the gate
13 h 30 apart on the timetable
FR 1206 leaves 13 h 30 after AA 740 arrives on the timetable: more than half a day, so not a connection we count.