AA 8762 then IB 1325 at Madrid
Valencia → Madrid → Düsseldorf
Timetable, Madrid time
07:10AA 8762 from Valencia at the gate
20:00IB 1325 to Düsseldorf leaves the gatealso LA 1529
12 h 50 apart on the timetable
IB 1325 leaves 12 h 50 after AA 8762 arrives on the timetable: more than half a day, so not a connection we count.