AA 9602 then FR 2753 at Madrid
Philadelphia → Madrid → Milan
Timetable, Madrid time
13:30AA 9602 from Philadelphia at the gate
12:35FR 2753 to Milan leaves the gate
23 h 05 apart on the timetable, overnight
FR 2753 leaves 23 h 05 after AA 9602 arrives on the timetable: more than half a day, so not a connection we count.